Where is terephthalic acid found?

Terephthalic acid (TPA) is made by air oxidation of p-xylene and requires purification for use in polyester fiber manufacture.

How is purified terephthalic acid made?

Modern technologies produce purified terephthalic acid by the catalytic liquid phase oxidation of paraxylene in acetic acid, in the presence of air. The process uses manganese or cobalt acetate as a catalyst. The reaction is exothermic, producing water which is removed in a solvent recovery system.

What is purified terephthalic acid?

Purified Terephthalic Acid (PTA) is an organic compound produced commercially through the oxidation of paraxylene by the oxygen in the air. A majority of PTA is consumed in the development of polyester resins, such as polyester films, polyester fiber & yarn, and PET material bottles.

What is purified terephthalic acid used for?

Purified terephthalic acid (PTA), one of the largest-volume commodity chemicals, is predominantly used for producing saturated polyesters, mainly polyethylene terephthalate (PET) and related polymer products such as fibers, resins, thin films, bottles, etc.

Is terephthalic acid made from crude oil?

Terephthalic acid (PTA) is one of the monomers used for the synthesis of the polyester, polyethylene terephthalate (PET), that is used for the large-scale manufacture of synthetic fibers and plastic bottles. PTA is largely produced from the liquid-phase oxidation of petroleum-derived p-xylene (PX).

Is terephthalic acid natural?

Biodegredation. In Comamonas thiooxydans strain E6, terephthalic acid is biodegraded by a pathway starting at terephthalate 1,2-dioxygenase into protocatechuic acid, a common natural product.

What is the raw material for PTA?

This white solid is a commodity chemical, used principally as a precursor to the polyester PET, used to make clothing and plastic bottles. Several million tonnes are produced annually….Terephthalic acid.

Names
Other names Terephthalic acid para-Phthalic acid TPA PTA BDC
Identifiers
CAS Number 100-21-0
3D model (JSmol) Interactive image

What is p-xylene made from?

p-Xylene is produced by catalytic reforming of petroleum naphtha as part of the BTX aromatics (benzene, toluene and the xylene isomers) extracted from the catalytic reformate.

Is purified terephthalic acid hazardous?

* Terephthalic Acid can affect you when breathed in. * Contact can irritate the skin and eyes. * Breathing Terephthalic Acid can irritate the nose, throat and lungs causing coughing, wheezing and/or shortness of breath. * Repeated exposure to Terephthalic Acid may affect the kidneys.

Why is it called terephthalic acid?

The common name is derived from the turpentine-producing tree Pistacia terebinthus and phthalic acid.

Where is xylene produced?

Xylene is an aromatic hydrocarbon that occurs naturally in petroleum and coal tar and is a constituent of smoke from most combustion sources. In the U.S., xylene is produced primarily using catalytic reforming of petroleum (approximately 95%).

How do you synthesize p-xylene?

The synthesis relies on the conversion of hexene (from trimerization of ethylene) to 2,4-hexadiene followed by a Diels–Alder reaction with ethylene to form 3,6-dimethylcyclohexene. This monoene is readily dehydrogenated to para-xylene uncontaminated by the ortho and meta isomers.